n-PENTANE
N-PENTANE provides high accuracy thermodynamic properties for normal pentane (Molar mass=72.147 g/mole) using the Fundamental Equation of State, as described by:
R.T. Jacobsen, S.G. Penoncello and E.W. Lemmon
Thermodynamic Properties of Cryogenic Fluids
Plenum Press, ISBN 0-306-45522-6, 1997
The equation of state is based upon the formulation developed by:
Span, R.,
"Multiparameter Equations of State - An Accurate Source of Thermodynamic of Property Data," Springer, Berlin, Heidelberg, New York, (2000). The parameters needed for this formulation were provided by Eric Lemmon at NIST, Boulder Co.
The specific heat of n-pentane in the ideal gas state is determined from
Jaeschke, M. and Schley, P.
"Ideal-Gas Thermodynamic Properties for Natural-Gas Applications"
Intl. Journal of Thermophysics, Vol. 16, No. 6, pp. 1381-1385, (1995)
Reference State
h = 0 kJ/kg, s = 0 kJ/kg-K at 298.15 K, 101.325 kPa. The reference state can be changed using the $Reference directive.
Range of applicability for equation of state:
177 K < T < 589 K
0 < P < 55 MPa
Thermal Conductivity and liquid viscosity correlations were fit to tabular data provided in:
"Properties of Inorganic and Organic Fluids"
Edited by C.Y. Ho
Authored by: P.E. Liley, T. Makita, and Y. Tanaka.
CINDAS Data Series of Material Properties, Vol V-1
Hemisphere Publishing Corporation
Chapter 26 - n-Pentane
Gas-phase viscosity is from:
"Recommended Values for the Viscosity in the Limit of Zero Density and its Initial Density Dependence for Twelve Gases and Vapors: Revisited from Experiment
between 297 K and 691 K"
Eckhard Vogel
J. Phys. Chem. Ref. Data 49, 043102 (2020); https://doi.org/10.1063/5.0023688
Range of applicability for transport function correlations:
Gas-phase viscosity: 290 K to 589 K
Liquid-phase viscosity: 177K to 470 K
Gas-phase thermal conductivity: 290 K to 589K
Liquid-phase thermal conductivity: 177K to 470 K
Surface tension data are provided through a correlation developed by:
G.R. Somayajulu
"A Generalized Equation for Surface Tension from the Triple Point to the Critical Point"
International Journal of Thermophysics, Vol. 9, No. 4, 1988
The melting pressure curve (valid for temperatures between 143.47 K and 251 K) is determined from:
Lide, D.R. and Kehiaian, H.V.,
CRC Handbook of Thermophysical and Thermochemical Data
CRC Press, 1994, ISBN 0-8493-0197-1, 5th printing